Synthesis and characterization of linear tetraphenyl-tetramethyldisiloxane diacetylene copolymers

被引:0
|
作者
Houser, EJ [1 ]
Keller, TM [1 ]
机构
[1] USN, Div Chem, Mat Chem Branch, Res Lab, Washington, DC 20375 USA
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暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
New phenyl substituted siloxyl diacetylene polymers have been prepared in high yields. The syntheses are one-pot, two step procedures involving the reaction of dilithiobutadiyne with various dichlorodisiloxanes. Spectroscopic and microanalytical data support the proposed structures. The polymers are thermally crosslinked to give hard, void-free thermosets which can be further heated to give ceramic products with high weight retention.
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页码:236 / 247
页数:12
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