Reaction of H• with H2O2 as observed by optical absorption of perhydroxyl radicals or aliphatic alcohol radicals and of •OH with H2O2.: A pulse radiolysis study

被引：20
|
作者：
Alam, MS
Kelm, M
Rao, BSM
Janata, E
机构：
[1] Hahn Meitner Inst Berlin GmbH, Bereich Solarenergieforsch, D-14109 Berlin, Germany
[2] Forschungszentrum Karlsruhe, Inst Nukl Entsorgung, D-76021 Karlsruhe, Germany
[3] Univ Pune, Dept Chem, Natl Ctr Free Rad Res, Pune, Maharashtra, India
来源：
RADIATION PHYSICS AND CHEMISTRY | 2004年 / 71卷 / 06期
关键词：
hydrogen peroxide; hydrogen atom; hydroxyl radical; aliphatic alcohol radicals; rate constants; pulse radiolysis;
D O I：
10.1016/j.radphyschem.2003.11.007
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two new procedures were employed for studying the reaction of hydrogen atoms with hydrogen peroxide. The absorption in the UV-range was observed either for an acidic aqueous solution containing only hydrogen peroxide or for a similar solution but also containing an aliphatic alcohol. From the increase in absorption of various alcohol radicals, a rate constant of 3.5 x 10(7) dm(3) mol(-1) s(-1) was determined. In addition, the rate constant for the reaction of hydroxyl radicals with hydrogen peroxide was determined to be 3.0 x 10(7) dm(3) mol(-1) s(-1). (C) 2003 Elsevier Ltd. All-rights reserved.
引用
收藏
页码：1087 / 1093
页数：7
相关论文
共 50 条
  • [21] CONSTRUCTION OF DISTRIBUTION FUNCTIONS OF OH RADICALS IN H2-O2 FLAME
    FERDINANDUS, J
    CZECHOSLOVAK JOURNAL OF PHYSICS, 1975, 25 (01) : 57 - 64
  • [22] Model for radiolysis of water and aqueous solutions of H2, H2O2 and O2
    Ershov, B. G.
    Gordeev, A. V.
    RADIATION PHYSICS AND CHEMISTRY, 2008, 77 (08) : 928 - 935
  • [23] A new form of H2O2.
    Geib, KH
    Harteck, P
    BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1932, 65 (08): : 1551 - 1555
  • [24] THE REACTION OF HEMIN WITH H2O2
    KREMER, ML
    EUROPEAN JOURNAL OF BIOCHEMISTRY, 1989, 185 (03): : 651 - 658
  • [25] Cells with Impaired Mitochondrial H2O2 Sensing Generate Less •OH Radicals and Live Longer
    Martins, Dorival
    Titorenko, Vladimir I.
    English, Ann M.
    ANTIOXIDANTS & REDOX SIGNALING, 2014, 21 (10) : 1490 - 1503
  • [26] Atmospheric formation of OH radicals and H2O2 from alkene ozonolysis under humid conditions
    Anglada, JM
    Aplincourt, P
    Bofill, JM
    Cremer, D
    CHEMPHYSCHEM, 2002, 3 (02) : 215 - +
  • [27] Roles of varied radicals in NO oxidation by Fe2+/H2O2 system
    College of Energy Science and Engineering, Harbin Institute of Technology, Harbin
    Heilongjiang
    150001, China
    不详
    Heilongjiang
    163318, China
    Huagong Xuebao, 1 (449-454):
  • [28] REACTION OF MAGNESIUM DIBORIDE WITH H2O, H2O2, AND ACIDS
    LYASHENKO, VI
    KOSOLAPOVA, TY
    SEREBRYAKOVA, TI
    INORGANIC MATERIALS, 1985, 21 (07) : 988 - 990
  • [29] Mechanism study on TiO2 inducing •O2- and O•H radicals in O3/H2O2 system for high-efficiency NO oxidation
    Meng, Fanyu
    Guo, Lina
    Zou, Haocheng
    Zhu, Boming
    Zhou, Fayang
    Zeng, Yiqing
    Han, Jiayou
    Yang, Jun
    Zhang, Shule
    Zhong, Qin
    JOURNAL OF HAZARDOUS MATERIALS, 2020, 399
  • [30] The water trimer reaction OH + (H2O)3 → (H2O)2OH + H2O
    Gao, Aifang
    Li, Guoliang
    Peng, Bin
    Weidman, Jared D.
    Xie, Yaoming
    Schaefer, Henry F.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2020, 22 (17) : 9767 - 9774
12345