Catalytic Synthesis and Stereostructure of 1,2,3-Trisubstituted Decahydroisoquinolines

被引:0
|
作者
Reshetov, P. V. [1 ]
Seller, R. V. [1 ]
Golikov, A. G. [1 ]
Skuratova, M. I. [1 ]
机构
[1] Razumovskii Saratov Med Univ, Ul B Kazachya 112, Saratov 410012, Russia
关键词
C-13; MAGNETIC-RESONANCE; SEMIEMPIRICAL METHODS; PARAMETERS; OPTIMIZATION; DERIVATIVES;
D O I
10.1134/S1070428017020130
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Liquid-phase catalytic reduction of 1,2,3-substituted 5,6,7,8-tetrahydroisoquinolinium perchlorates was investigated. The reaction proceeds stereodirectionally affording cis-decahydroisoquinolines. The probable scheme of reaction products formation is suggested. The structure of compounds obtained was established by IR and C-13 NMR spectroscopy.
引用
收藏
页码:222 / 225
页数:4
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