Ion transfer at a micro water nitrophenyl octyl ether interface

被引：20
|
作者：
Quinn, B [1 ]
Lahtinen, R [1 ]
Kontturi, K [1 ]
机构：
[1] Helsinki Univ Technol, Phys Chem & Electrochem Lab, FIN-02015 HUT, Finland
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1997年 / 436卷 / 1-2期
基金：
芬兰科学院;
关键词：
micro water/NPOE interface; ion transfer; kinetics;
D O I：
10.1016/S0022-0728(97)00358-6
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The kinetics of the tetraethylammonium ion (TEA(+)) transfer at the microhole supported water (w)/o-nitrophenyloctyl ether (NPOE) interface were investigated using steady state voltammetry. Methods proposed in the literature for the determination of quasi-reversible kinetics at metallic microelectrodes were considered. These methods are based on a comparison of the reversible system with the experimental system as the size of the electrode is varied. This approach was found to be unsuitable for the case of ion transfer at the micro w/NPOE interface. (C) 1997 Elsevier Science S.A.
引用
收藏
页码：285 / 290
页数：6
相关论文
共 50 条
  • [31] Ion-Transfer Voltammetry at Fluorous Ether | Water Interfaces
    Uematsu, Kohei
    Matsubara, Yuka
    Katano, Hajime
    Osakai, Toshiyuki
    ANALYTICAL SCIENCES, 2021, 37 (10) : 1379 - 1383
  • [32] DIELECTRIC BEHAVIOR OF PVC MEMBRANES PLASTICIZED WITH DIOCTYL SEBACATE OR ORTHO-NITROPHENYL-OCTYL ETHER
    DULIC, N
    HORVATH, L
    HORVAI, G
    TOTH, K
    PUNGOR, E
    ELECTROANALYSIS, 1990, 2 (07) : 533 - 537
  • [33] Extraction of heptavalent technetium from nuclear waste streams with 2-nitrophenyl octyl ether
    Chen, J
    Boerrigter, H
    Veltkamp, AC
    RADIOCHIMICA ACTA, 2001, 89 (06) : 407 - 411
  • [34] Ion-Transfer Voltammetry at Fluorous Ether | Water Interfaces
    Kohei Uematsu
    Yuka Matsubara
    Hajime Katano
    Toshiyuki Osakai
    Analytical Sciences, 2021, 37 : 1379 - 1383
  • [35] ION TRANSFER ACROSS THE IMMISCIBLE WATER BENZONITRILE INTERFACE
    ALEMU, H
    SOLOMON, T
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1989, 261 (2A): : 297 - 300
  • [36] Standard ion transfer potential at the water|butyronitrile interface
    Riva, J. S.
    Bassetto, V. C.
    Girault, H. H.
    Olaya, A. J.
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2019, 835 : 192 - 196
  • [37] KINETICS OF THE TRANSFER OF PICRATE ION AT THE WATER NITROBENZENE INTERFACE
    OSAKAI, T
    KAKUTANI, T
    SENDA, M
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1985, 58 (09) : 2626 - 2633
  • [38] VOLTAMMETRIC STUDY OF ION TRANSFER ACROSS THE WATER ORTHO-NITROPHENYLOCTYL ETHER INTERFACE .1. REVERSIBLE PROCESS
    VALENT, O
    KORYTA, J
    PANOCH, M
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1987, 226 (1-2) : 21 - 25
  • [39] A study of tetraethylammonium ion transfer across a micro liquid/liquid interface
    Tong, YH
    Shao, YH
    Wang, EK
    CHINESE JOURNAL OF ANALYTICAL CHEMISTRY, 2001, 29 (11) : 1241 - 1245
  • [40] Noise Analysis of Ion Transfer Kinetics at the Micro Liquid/Liquid Interface
    Josypcuk, Oksana
    Holub, Karel
    Marecek, Vladimir
    XXXV MODERNI ELEKTROCHEMICKE METODY, 2015, : 95 - 99
12345