Effects of Cr2O3 Addition on Microstructure and Vacuum Flashover Performance of Glass-ceramics

被引:6
|
作者
Zhang, Hao [1 ]
Xu, Yan [1 ]
Qiao, Guanjun [1 ]
Ma, Dongdong [2 ]
Jin, Haiyun [2 ]
机构
[1] Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Sch Mat Sci & Engn, Xian 710049, Shaanxi, Peoples R China
[2] Xi An Jiao Tong Univ, State Key Lab Elect Insulat & Power Equipment, Sch Elect Engn, Xian 710049, Shaanxi, Peoples R China
基金
中国国家自然科学基金;
关键词
Flashover; glass-ceramic; chromium oxide; vacuum insulation; SURFACE-PROPERTIES;
D O I
10.1109/TDEI.2014.004296
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
K2O-MgO-SiO2-Al2O3-B2O3-F/Cr2O3 glass-ceramics with higher flashover voltage were fabricated by sintering method. The electrical properties were measured, it was found that the flashover voltage was improved obviously with addition of small amount of Cr2O3. The crystalline phases were identified by XRD and the microstructures were observed by SEM and BSE, the results showed that, there were Cr2O3 "islands" existed on the surface of ceramics. These "islands" could absorb the secondary electron and form the secondary electron "black hole". The electric field distribution on surface was also simulated based on BSE and SEM results by ANSYS, it was showed that the Cr2O3 "islands" also distorted the surface electrical field. Therefore, the flashover voltage was increased. When adding with 3wt% Cr2O3, the hold-off voltage of glass-ceramics reached to 57 kV cm(-1) (improved by 45%).
引用
收藏
页码:1882 / 1886
页数:5
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