Dual Rh-Ru Catalysts for Reductive Hydroformylation of Olefins to Alcohols

被引：31

作者：

Rodrigues, Fabio M. S. ^{[1
]}

Kucmierczyk, Peter K. ^{[2
,3
]}

Pineiro, Marta ^{[1
]}

Jackstell, Ralf ^{[2
]}

Franke, Robert ^{[3
,4
]}

Pereira, Mariette M. ^{[1
]}

Beller, Matthias ^{[2
]}

机构：

[1] Univ Coimbra, Dept Quim, CQC, Rua Larga, P-3004535 Coimbra, Portugal

[2] Univ Rostock, Leibniz Inst Katalyse EV, Albert Einstein Str 29a, D-18059 Rostock, Germany

[3] Ruhruniv Bochum, Lehrstuhl Theoret Chem, Univ Str 150, D-44801 Bochum, Germany

[4] Evonik Ind AG, Paul Baumann Str 1, D-45772 Marl, Germany

来源：

CHEMSUSCHEM | 2018年 / 11卷 / 14期

基金：

欧盟地平线“2020”;

关键词：

alcohols; homogeneous catalysis; rhodium; ruthenium; tandem reactions; INTERNAL ALKENES; CARBON-DIOXIDE; COMPLEXES; TRANSESTERIFICATION; BIODIESEL; LIGANDS; ANION; OIL;

D O I：

10.1002/cssc.201800488

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An active and selective dual catalytic system to promote domino hydroformylation-reduction reactions is described. Apart from terminal, di- and trisubstituted olefins, for the first time the less active internal C-C double bond of tetrasubstituted alkenes can also be utilized. As an example, 2,3-dimethylbut-2-ene is converted into the corresponding n-alcohol with high yield (90%) as well as regio- and chemoselectivity (>97%). Key for this development is the use of a combination of Rh complexes with bulky monophosphite ligands and the Ru-based Shvo's complex. A variety of aromatic and aliphatic alkenes can be directly used to obtain mainly linear alcohols.

引用

页码：2310 / 2314

页数：5

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