Physicochemical investigation on the complexes of Co(II), Ni(II) and Cu(II) with aminocyclodiphosph(v)azane derivative

被引：9
|
作者：
Abd-Ellah, IM [1 ]
El-Sayed, BA [1 ]
El-Nawawy, MA [1 ]
机构：
[1] Al Azhar Univ, Fac Sci, Dept Chem, Cairo, Egypt
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2002年 / 177卷 / 12期
关键词：
aminocyclodiphosph(V)azane metal complexes; electronic mass spectra; IR; magnetic moment;
D O I：
10.1080/10426500214880
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Co(II), Ni(II) and Cu(II) form 2: 1 complexes with aminocyclodiphosph(V)azane derivative. The complexes have been investigated in solution by the spectrophometric molar ratio and conductometeric methods. The ligand and its complexes have been isolated in solid state and characterized on the basis of microanalytical, infrared, electronic, magnetic moment, H-1 NMR and mass spectral data. The cobalt and nickel complexes were assigned to be in tetrahedral structure while the copper complex is assigned to be in square planar.
引用
收藏
页码：2895 / 2906
页数：12
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