Ladder structure of a lithium organyl:: Synthesis and crystal structure of a mixed aggregate of n-BuLi and an (aminomethyl) (lithiomethyl)silane

被引：20

作者：

Strohmann, C ^{[1
]}

Abele, BC ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 20期

关键词：

D O I：

10.1021/om0005957

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A mixture of n-BuLi and the (aminomethy)-(lithiomethyl)silane 3 shows a higher reactivity than the separate compounds. A single-crystal X-ray structure of the mixed aggregate between n-BuLi and the (lithiomethyl)silane ([3.n-BuLi](2)) establishes a Ladder structure of the lithiumorganyl in the solid state.

引用

页码：4173 / 4175

页数：3

共 50 条

[31] Synthesis and Crystal Structure of a Novel Ladder-like Organooxotin Cluster from 2,4,6-Trimethylbenzolic Acid and N-Benzylhydroxylamine
张春华
陈满生
李薇
杨颖群
邝代治
邓奕芳
结构化学, 2007, (01) : 41 - 44
[32] Synthesis, crystal structure, and luminescent property of a new Zn(II) compound based on mixed polycarboxylate and N-donor ligands
Liu, Hui-Min
INORGANIC AND NANO-METAL CHEMISTRY, 2017, 47 (01) : 95 - 98
[33] Synthesis and crystal structure of a new lithium nickel fluorophosphate Li2[NiF(PO4)] with an ordered mixed anionic framework
Dutreilh, M
Chevalier, C
El-Ghozzi, M
Avignant, D
Montel, JM
JOURNAL OF SOLID STATE CHEMISTRY, 1999, 142 (01) : 1 - 5
[34] SYNTHESIS, CRYSTAL-STRUCTURE, AND ELECTROCHEMICAL PROPERTIES OF MU-(2,5-BIS[N,N-BIS(2'-PYRIDYLMETHYL)AMINOMETHYL]PYRAZINE)-BIS[CHLOROCOPPER(II)] PERCHLORATE
OSHIO, H
TORIUMI, K
HAYASHI, Y
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (01): : 293 - 298
[35] Tetrameric di(-tert-butylamino)di(-N-lithiomethylamino) silane, (Me(3)CHN)(2)Si(NLiMe)(2) - Synthesis and crystal structure
Rakebrandt, HJ
Klingebiel, U
Noltemeyer, M
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1997, 623 (02): : 288 - 291
[36] Synthesis of the [Co(N-(3-aminoethyl)-1, 3-propanediamine) (2-aminomethyl)pyridine)Cl][ZnCl4] and crystal structure of an isomer
Tao, Z
Zhu, QJ
Zheng, YQ
Xu, YZ
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2000, 16 (04) : 631 - 636
[37] Synthesis, crystal structure, and properties of a new cadmium(II) polymer with mixed Cl-/SCN- ligands: [CdCl(SCN)]n
Zhang, Jian-Jun
JOURNAL OF COORDINATION CHEMISTRY, 2010, 63 (07) : 1139 - 1146
[38] Mixed phosphine/N-heterocyclic carbene–palladium complexes: synthesis, characterization, crystal structure and application in the Sonogashira reaction in aqueous media
Aydın Aktaş
Fatoş Erdemir
Duygu Barut Celepci
Yetkin Gök
Muhittin Aygün
Transition Metal Chemistry, 2019, 44 : 229 - 236
[39] Synthesis and X-ray crystal structure of the first mononuclear nickel(II) alkane thiolate complex with a mixed (S,N,N,O) ligand field
Berkessel, A
Bolte, M
Neumann, T
Seidel, L
CHEMISCHE BERICHTE, 1996, 129 (10) : 1183 - 1189
[40] Synthesis, characterization, and crystal structure of the copper(II) complex of the optical active polypyridylmethylamine ligand:: N,N,N′-tris(2-pyridylmethyl)-S-2-(aminomethyl) piperidine = S-P3pipda
Kurosaki, H
Koike, H
Mori, S
Ogata, Y
Yamaguchi, Y
Goto, M
INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (11) : 1229 - 1232

← 1 2 3 4 5 →