Ladder structure of a lithium organyl:: Synthesis and crystal structure of a mixed aggregate of n-BuLi and an (aminomethyl) (lithiomethyl)silane

被引：20

作者：

Strohmann, C ^{[1
]}

Abele, BC ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 20期

关键词：

D O I：

10.1021/om0005957

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A mixture of n-BuLi and the (aminomethy)-(lithiomethyl)silane 3 shows a higher reactivity than the separate compounds. A single-crystal X-ray structure of the mixed aggregate between n-BuLi and the (lithiomethyl)silane ([3.n-BuLi](2)) establishes a Ladder structure of the lithiumorganyl in the solid state.

引用

页码：4173 / 4175

页数：3

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