Activation of Pd-precatalysts by organic compounds for vinyl-addition polymerization of a norbornene derivative†

被引：7

作者：

Karpov, Gleb O. ^{[1
]}

Ren, Xiang-Kui ^{[2
]}

Melnikova, Elizaveta K. ^{[3
,4
]}

Bermeshev, Maxim V. ^{[1
]}

机构：

[1] RAS, AV Topchiev Inst Petrochem Synth, 29 Leninskii Prospect, Moscow 119991, Russia

[2] Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300350, Peoples R China

[3] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Vavilov St 28, Moscow 119991, Russia

[4] Moscow MV Lomonosov State Univ, Dept Chem, Leninskie Gory 1, Moscow, Russia

来源：

CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 35期

关键词：

PALLADIUM; POLYMERS; OLEFINS; NICKEL;

D O I：

10.1039/d1cc00546d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An approach to activating Pd-complexes without using additives such as Lewis acids has been developed for addition polymerization of norbornenes. Aryl iodides and aryl diazonium salts were efficiently applied as cocatalysts to Pd(0)- and Pd(2+)-complexes. The developed systems catalyzed polymerization of norbornenes containing bulky and polar functional groups both in an inert atmosphere and air resulting in soluble and high-molecular-weight saturated polymers.

引用

页码：4255 / 4258

页数：4

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