Activation of Pd-precatalysts by organic compounds for vinyl-addition polymerization of a norbornene derivative†

被引：7

作者：

Karpov, Gleb O. ^{[1
]}

Ren, Xiang-Kui ^{[2
]}

Melnikova, Elizaveta K. ^{[3
,4
]}

Bermeshev, Maxim V. ^{[1
]}

机构：

[1] RAS, AV Topchiev Inst Petrochem Synth, 29 Leninskii Prospect, Moscow 119991, Russia

[2] Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300350, Peoples R China

[3] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Vavilov St 28, Moscow 119991, Russia

[4] Moscow MV Lomonosov State Univ, Dept Chem, Leninskie Gory 1, Moscow, Russia

来源：

CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 35期

关键词：

PALLADIUM; POLYMERS; OLEFINS; NICKEL;

D O I：

10.1039/d1cc00546d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An approach to activating Pd-complexes without using additives such as Lewis acids has been developed for addition polymerization of norbornenes. Aryl iodides and aryl diazonium salts were efficiently applied as cocatalysts to Pd(0)- and Pd(2+)-complexes. The developed systems catalyzed polymerization of norbornenes containing bulky and polar functional groups both in an inert atmosphere and air resulting in soluble and high-molecular-weight saturated polymers.

引用

页码：4255 / 4258

页数：4

共 50 条

[1] Single-Component Catalysts for the Vinyl-Addition Polymerization of Norbornene and its Derivatives
Bermesheva, Evgeniya V.
Bermeshev, Maxim V.
CHEMCATCHEM, 2023, 15 (24)
[2] Vinyl-Addition Polymerization of Norbornene Catalyzed by Chelating (Pyridyl)imine Metal Complexes
van der Westhuizen, Barend D.
Kumah, Robert T.
Herres-Pawlis, Sonja
Ojwach, Stephen O.
CHEMISTRYSELECT, 2025, 10 (13):
[3] Pd(II) complexes bearing di- and monochelate fluorinated β-ketonaphthyliminato ligand and their catalytic properties towards vinyl-addition polymerization and copolymerization of norbornene and ester-functionalized norbornene derivative
Tian, Jianwen
Zhu, Hongyu
Liu, Jingyin
Chen, Defu
He, Xiaohui
APPLIED ORGANOMETALLIC CHEMISTRY, 2014, 28 (09) : 702 - 711
[4] Metal catalysts for the vinyl/addition polymerization of norbornene
Blank, Frederik
Janiak, Christoph
COORDINATION CHEMISTRY REVIEWS, 2009, 253 (7-8) : 827 - 861
[5] Synthesis and nonlinear-optical properties of vinyl-addition poly(norbornene)s
Park, KH
Twieg, RJ
Ravikiran, R
Rhodes, LF
Shick, RA
Yankelevich, D
Knoesen, A
MACROMOLECULES, 2004, 37 (14) : 5163 - 5178
[6] Vinyl-addition polymerization of norbornene catalyzed by (pyrazol-1-ylmethyl)pyridine divalent iron, cobalt and nickel complexes
Benade, Letitia L.
Ojwach, Stephen O.
Obuah, Collins
Guzei, Ilia A.
Darkwa, James
POLYHEDRON, 2011, 30 (17) : 2878 - 2883
[7] Highly efficient vinylic addition polymerization of 5-vinyl-2-norbornene using benzylic palladium complexes as precatalysts
Perez-Ortega, Ignacio
Albeniz, Ana C.
POLYMER CHEMISTRY, 2021, 12 (41) : 5963 - 5969
[8] Dielectric Properties of Metathesis and Vinyl-addition 5-Cyclohexyl-2-norbornene Polymers
Zotkin, M. A.
Wozniak, A. I.
Alentiev, D. A.
Lunev, I. V.
Galiullin, A. A.
Bermeshev, M. V.
RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2023, 96 (07) : 728 - 736
[9] Palladium(II) and copper(II) chloride complexes bearing bulky α-diimine ligands as catalysts for norbornene vinyl-addition (co)polymerization
Tian, Jianwen
He, Xiaohui
Liu, Jingyin
Deng, Xiaodan
Chen, Defu
RSC ADVANCES, 2016, 6 (27) : 22908 - 22916
[10] Air-Stable Single-Component Pd-Catalysts for Vinyl-Addition Polymerization of Functionalized Norbornenes
Bermesheva, Evgeniya V.
Medentseva, Ekaterina I.
Khrychikova, Anna P.
Wozniak, Alyona I.
Guseva, Marina A.
Nazarov, Ivan V.
Morontsev, Alexander A.
Karpov, Gleb O.
Topchiy, Maxim A.
Asachenko, Andrey F.
Danshina, Anastasia A.
Nelyubina, Yulia V.
Bermeshev, Maxim V.
ACS CATALYSIS, 2022, 12 (24) : 15076 - 15090

← 1 2 3 4 5 →