Nanoscale Hollow Spheres of an Amphiphilic Mixed (Phthalocyaninato)(porphyrinato)europium Double-Decker Complex

被引：14
|
作者：
Lu, Guifen [1 ,2 ]
Ou, Zhongping [2 ]
Jiang, Jianzhuang [1 ]
Bian, Yongzhong [1 ]
机构：
[1] Univ Sci & Technol Beijing, Dept Chem, Beijing 100083, Peoples R China
[2] Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Peoples R China
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 05期
关键词：
Phthalocyanines; Porphyrinoids; Sandwich complexes; Nanostructures; Self-assembly; Rare earths; SELF-ASSEMBLED NANOSTRUCTURES; SPECTROSCOPIC CHARACTERIZATION; INTERMOLECULAR INTERACTION; PORPHYRINATO LIGANDS; CATIONIC PORPHYRINS; PHTHALOCYANINE; VESICLES; ORGANIZATION; FABRICATION; NANOTUBES;
D O I：
10.1002/ejic.200900851
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel amphiphilic sandwich-type mixed (phthalocyaninato)(porphyrinato)europium double-decker complex Eu(Pc)-[T(OH)(3)PP] [Pc = phthalocyaninate, T(OH)(3)PP = 5,10,15-tris(4-hydroxyphenyl)-20-(4-tert-butylphenyl)porphyrinate] (1) was designed, prepared, and characterized by a range of spectroscopic methods in addition to elemental analysis. By employing a solution injection method, this compound self-assembles into nanoscale hollow spheres with an average diameter of ca. 70 nm. The hollow spherical structure was determined by transmission electronic microscopy and scanning electronic microscopy. Comparison in the electronic absorption spectrum between the aggregate and the compound itself in solution reveals the J-aggregation packing mode of the amphiphilic double-decker molecules in nanoscale hollow spheres. The present work represents the first example of nanoscale hollow sphere morphology self-assembled from sandwich tetrapyrrole rare-earth complexes.
引用
收藏
页码：753 / 757
页数：5
相关论文
共 50 条
  • [11] Effect of Protonation on the Single-molecule-magnet Behavior of a Mixed (Phthalocyaninato)(porphyrinato)terbium Double-decker Complex
    Tanaka, Daisuke
    Sumitani, Nobuto
    Inose, Tomoko
    Tanaka, Hirofumi
    Ishikawa, Naoto
    Ogawa, Takuji
    CHEMISTRY LETTERS, 2015, 44 (05) : 668 - 670
  • [12] C60-modified mixed (phthalocyaninato)(porphyrinato) yttrium(III) double-decker complex: Synthesis, characterization, and photophysical properties
    Li, Likun
    Zhang, Xianyao
    He, Xiaochuan
    Lu, Wenxin
    Yang, Liguo
    Bian, Yongzhong
    Weng, Yuxiang
    Jiang, Jianzhuang
    DYES AND PIGMENTS, 2014, 102 : 257 - 262
  • [13] Vibrational spectra of mixed (phthalocyaninato)(porphyrinato) yttrium(III) double-decker complexes: Density functional theory calculations
    Zhang, Yuexing
    Qi, Dongdong
    Cai, Xue
    Jiang, Jianzhuang
    VIBRATIONAL SPECTROSCOPY, 2009, 51 (02) : 184 - 192
  • [14] Magnetic investigations over reversibly switched chiral (phthalocyaninato)(porphyrinato) dysprosium double-decker compounds
    Sun, Nana
    Wang, Hailong
    Liu, Tao
    Qi, Dongdong
    Jiang, Jianzhuang
    DALTON TRANSACTIONS, 2019, 48 (05) : 1586 - 1590
  • [15] Highly ordered sandwich-type (phthalocyaninato) (porphyrinato) europium double-decker nanotubes and room temperature NO2 sensitive properties
    Zhu, Peihua
    Wang, Yucheng
    Ma, Pan
    Song, Feifei
    Han, Xinyu
    Yao, Shuncheng
    Yang, Cheng
    DALTON TRANSACTIONS, 2017, 46 (05) : 1531 - 1538
  • [16] Linkage effects to nonlinear optical properties of porphyrin-appended mixed (porphyrinato)(phthalocyaninato) yttrium(III) double-decker complexes
    Li, Yong
    Zhang, Xianyao
    Yan, Xingzhong
    Bian, Yongzhong
    Jiang, Jianzhuang
    LINEAR AND NONLINEAR OPTICS OF ORGANIC MATERIALS XI, 2011, 8113
  • [17] Synthesis, crystal structure and self-assembly property of a mixed (phthalocyaninato) (porphyrinato) europium triple-decker complex
    Lu, Jitao
    Zhang, Daopeng
    Wang, Hailong
    Jiang, Jianzhuang
    Zhang, Xiaomei
    INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (10) : 1144 - 1147
  • [18] Mixed (porphyrinato)(phthalocyaninato) rare-earth(III) double-decker complexes for broadband light harvesting organic solar cells
    Li, Yong
    Bian, Yongzhong
    Yan, Ming
    Thapaliya, Prem S.
    Johns, Daniel
    Yan, Xingzhong
    Galipeau, David
    Jiang, Jianzhuang
    JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (30) : 11131 - 11141
  • [19] Isolation and Spectroscopic Characterization of Protonated Mixed [Tetrakis (4-pyridyl)porphyrinato] (phthalocyaninato)Rare Earth (Ⅲ)Double-decker Compounds
    JIANG Jian-zhuang
    Department of Chemistry
    Chemical Research in Chinese Universities, 2001, (02) : 134 - 142
  • [20] Synthesis, Characterization and OFET Properties of Amphiphilic Mixed (Phthalocyaninato)(porphyrinato)europium(III) Complexes
    Ma, Pan
    Chen, Yanli
    Sheng, Ning
    Bian, Yongzhong
    Jiang, Jianzhuang
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (07) : 954 - 960
12345