Design of a novel inherently chiral calix[4]arene for chiral molecular recognition

被引：98
|
作者：
Shirakawa, Seiji
Moriyama, Akihiro
Shimizu, Shoichi [1 ]
机构：
[1] Nihon Univ, Coll Ind Technol, Dept Appl Mol Chem, Narashino, Chiba 2758575, Japan
[2] Nihon Univ, Coll Ind Technol, High Technol Res Ctr, Narashino, Chiba 2758575, Japan
来源：
ORGANIC LETTERS | 2007年 / 9卷 / 16期
关键词：
D O I：
10.1021/ol071249p
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[GRAPHICS] A newly designed inherently chiral calix[4]arene was synthesized and resolved to an optically pure form. Enantiomeric recognition ability of the chiral calix[4]arene was examined using H-1 NMR experiments with mandelic acid. In addition, the chiral calix[4]arene was applied to asymmetric reactions, as an organocatalyst.
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页码：3117 / 3119
页数：3
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