Synthesis of Diaryl Sulfides by Using Tetramethylthiuram Monosulfide (TMTM) as Organosulfur Source: A Practical C(sp2)-S Bond Construction

被引：1

作者：

Wang, Xi ^{[1
]}

Chen, Jin-Quan ^{[1
]}

Yang, Xing-Xing ^{[1
]}

Hao, Er-Jun ^{[2
]}

Dong, Zhi-Bing ^{[1
,2
,3
,4
,5
]}

机构：

[1] Wuhan Inst Technol, Sch Chem & Environm Engn, Wuhan 430205, Peoples R China

[2] Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China

[3] Wuhan Inst Technol, Minist Educ, Key Lab Green Chem Proc, Wuhan 430205, Peoples R China

[4] Wuhan Inst Technol, Hubei Key Lab Novel Reactor & Green Chem Technol, Wuhan 430205, Peoples R China

[5] Wuhan Inst Technol, Minist Educ, Engn Res Ctr Phosphorus Resources Dev & Utilizat, Wuhan 430205, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 2022卷 / 18期

关键词：

Catalysis; Iodobenzene; Phenylboronic acid; Synthesis; Tetramethylthiuram monosulfide; THIURAM SULFUR DONORS; DEOXYGENATION; DISULFIDES; SULFOXIDES;

D O I：

10.1002/ejoc.202200015

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A protocol for synthesizing symmetrical thioethers by using a cheap organosulfur reagent (tetramethylthiuram monosulfide: TMTM) was developed. Both iodobenzenes and phenylboronic acids react well with TMTM, giving the target products with good to excellent yields. This method features simple performance, wide functional group tolerance, and good to excellent yields, showing a potential application value for the synthesis of drug molecules.

引用

页数：7

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