An Efficient Copper-Catalyzed C(sp2)-S Formation Starting from Aryl Iodides and Tetramethylthiuram Monosulfide (TMTM)

被引：7
|
作者：
Wu, Yue-Xiao [1 ]
Peng, Kang [1 ]
Li, Jing-Hang [1 ]
Dong, Zhi-Bing [1 ,2 ,3 ,4 ]
机构：
[1] Wuhan Inst Technol, Sch Chem & Environm Engn, Wuhan 430205, Peoples R China
[2] Wuhan Inst Technol, Key Lab Green Chem Proc, Minist Educ, Wuhan 430205, Peoples R China
[3] Hubei Univ, Key Lab Synth & Applicat Organ Funct, Minist Educ, Wuhan 430062, Peoples R China
[4] Wuhan Inst Technol, Hubei Key Lab Novel Reactor & Green Chem Technol, Wuhan 430205, Peoples R China
来源：
SYNTHESIS-STUTTGART | 2020年 / 52卷 / 20期
关键词：
aryl iodide; thiuram; sulfur; bond formation; dithiocarbamates; TETRAALKYLTHIURAM DISULFIDES; S-ARYLATION; ANTIFUNGAL ACTIVITY; ARYLBORONIC ACIDS; DERIVATIVES; ZINC; ISOTHIOCYANATES; THIOAMIDES; CHEMISTRY; REAGENTS;
D O I：
10.1055/s-0040-1707899
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new, efficient copper-catalyzed C(sp(2))-S formation of phenyl dithiocarbamates starting from aryl iodides and tetramethylthiuram monosulfide (TMTM) was developed. The target compounds, phenyl dithiocarbamates with active sites, were synthesized smoothly in good to excellent yields. The easy performance, high yields, decent functional group compatibility, and cost-effective substrates make the protocol practical and attractive in C-S bond formation.
引用
收藏
页码：3001 / 3006
页数：6
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