Water-soluble organometallic complexes of tantalum:: Can alkyl and aqua ligands coexist in its coordination sphere?

被引：20
|
作者：
Conde, Ana
Fandos, Rosa
Otero, Antonio
Rodriguez, Ana
机构：
[1] Univ Castilla La Mancha, Dept Quim Inorgan Organ & Bioquim, Fac Ciencias Med Ambiente, Toledo 45071, Spain
[2] Univ Castilla La Mancha, Fac Quim, Dept Quim Inorgan Organ & Bioquim, Ciudad Real 13071, Spain
[3] Univ Castilla La Mancha, Dept Quim Inorgan Organ & Bioquim, Fac Quim, Ciudad Real 13071, Spain
[4] Univ Castilla La Mancha, ETS Ingn Ind, E-13071 Ciudad Real, Spain
来源：
ORGANOMETALLICS | 2007年 / 26卷 / 07期
关键词：
D O I：
10.1021/om0701165
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complexes [Cp*TaMe(OCH2)(2)py(H2O)]OTf (3), [Cp*Ta(OH)(OCH2)(2)py(H2O)]OTf (4), and [Cp*Ta(OCH2)(2)py(H2O)(2)]OTf2 (5) are described as the first examples of water-soluble organometallic derivatives of tantalum.
引用
收藏
页码：1568 / 1570
页数：3
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