Palladium-catalysed regio- and stereoselective annulation of allenyl stannanes by beta-iodo vinylic acids gives the corresponding alpha-pyrones in high yields. This annulation most probably proceeds through a Stille reaction/cyclisation sequence.
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Department of Chemistry, University of Illinois, Urbana-Champaign, 600 S. Mathews, Urbana, 61801, ILDepartment of Chemistry, University of Illinois, Urbana-Champaign, 600 S. Mathews, Urbana, 61801, IL
Kohler D.G.
Gockel S.N.
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Department of Chemistry, University of Illinois, Urbana-Champaign, 600 S. Mathews, Urbana, 61801, ILDepartment of Chemistry, University of Illinois, Urbana-Champaign, 600 S. Mathews, Urbana, 61801, IL
Gockel S.N.
Kennemur J.L.
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Department of Chemistry, University of Illinois, Urbana-Champaign, 600 S. Mathews, Urbana, 61801, ILDepartment of Chemistry, University of Illinois, Urbana-Champaign, 600 S. Mathews, Urbana, 61801, IL
Kennemur J.L.
Waller P.J.
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Department of Chemistry, University of Illinois, Urbana-Champaign, 600 S. Mathews, Urbana, 61801, ILDepartment of Chemistry, University of Illinois, Urbana-Champaign, 600 S. Mathews, Urbana, 61801, IL
Waller P.J.
Hull K.L.
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Department of Chemistry, University of Illinois, Urbana-Champaign, 600 S. Mathews, Urbana, 61801, ILDepartment of Chemistry, University of Illinois, Urbana-Champaign, 600 S. Mathews, Urbana, 61801, IL