Effect of heating of the electronic subsystem on the thermal stability of the C60 and C20 fullerenes and (C20)2 cluster molecule

被引:1
|
作者
Davydov, I. V. [1 ]
机构
[1] State Univ, Moscow Engn Phys Inst, Moscow 115409, Russia
关键词
D O I
10.1134/S1063783407060297
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The effect of heating of the electronic subsystem on the thermal stability of C-60 and C-20 fullerenes and a (C-20)(2) cluster molecule is investigated theoretically. It is demonstrated that the excitation of electrons to upper energy levels in accordance with the Fermi-Dirac distribution function does not lead to a substantial change in the activation energy E-a for decay of the C-20 fullerene. The stability of the C-60 Fullerene and the (C-20)(2) cluster molecule likewise does not change radically. However, the inclusion of corrections associated with the finite sizes of the heat bath leads to the activation energy E-a which is in better agreement with the calculated height of the potential barrier preventing the cluster decay.
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收藏
页码:1201 / 1206
页数:6
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