Synthesis of multivalent oxamate ligands based on calix[4]arene and thiacalix[4]arene backbones in 1,3-Alternate conformation

被引：4

作者：

Noamane, Mohamed Habib ^{[1
,2
]}

Ferlay, Sylvie ^{[1
]}

Abidi, Rym ^{[2
]}

Hosseini, Mir Wais ^{[1
]}

机构：

[1] Univ Strasbourg, Mol Tecton Lab, CNRS, CMC UMR 7140, F-67000 Strasbourg, France

[2] Univ Carthage, LACReSNE, Unite Interact Mol Specif, Fac Sci Bizerte, Bizerte 7021, Tunisia

来源：

TETRAHEDRON | 2017年 / 73卷 / 30期

关键词：

Calix[4]arenes; Thiacalix[4]arenes; Oxamate ligand; 1,3-Alternate conformation; Phthalimide; SILVER COORDINATION NETWORKS; MOLECULAR TECTONICS; DICOPPER(II) METALLACYCLOPHANES; COMPLEXATION PROPERTIES; DERIVATIVES; ALKALI; METAL; THIACALIXARENES; DESIGN;

D O I：

10.1016/j.tet.2017.05.043

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Five new multivalent ligands based on either p-tert-butylthiacalix[4]arene (TCA) 1 or p-tert-butylcalix[4] arene (CA) 2 backbones in 1,3-Alternate conformation bearing four oxamate coordinating groups at their lower rim were designed and synthesized by a multistep strategy. These ligands differ either by the nature of the calix[4]arene backbone (CA or TCA) or by the nature of the spacer ((CH2)(n)) connecting the oxamate binding units to the backbone. (C) 2017 Elsevier Ltd. All rights reserved.

引用

页码：4259 / 4264

页数：6

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