Kinetic comparison of isomeric oligo(ethylene oxide) (meth)acrylates: Aqueous polymerization of oligo(ethylene oxide) methyl ether methacrylate and methyl 2-(oligo(ethylene oxide) methyl ether)acrylate macromonomers

被引：0
|
作者：
Martinez, Michael R. [1 ]
Dworakowska, Sylwia [1 ,2 ]
Gorczynski, Adam [1 ,3 ]
Szczepaniak, Grzegorz [1 ]
Bossa, Ferdinando De Luca [1 ]
Matyjaszewski, Krzysztof [1 ]
机构：
[1] Carnegie Mellon Univ, Ctr Macromol Engn, Dept Chem, 4400 Fifth Ave, Pittsburgh, PA 15213 USA
[2] Cracow Univ Technol, Fac Chem Engn & Technol, Dept Biotechnol & Renewable Mat, Krakow, Poland
[3] Adam Mickiewicz Univ, Fac Chem, Poznan, Poland
来源：
JOURNAL OF POLYMER SCIENCE | 2022年 / 60卷 / 12期
基金：
美国安德鲁·梅隆基金会; 美国国家科学基金会;
关键词：
bottlebrushes; kinetics; macromonomer; methacrylate; PET-RAFT; FREE-RADICAL POLYMERIZATION; MOLECULAR BRUSHES; RAFT POLYMERIZATION; CHAIN TRANSFER; SOLVENT-FREE; COPOLYMERS; BEHAVIOR; ATRP; DISPROPORTIONATION; COMB;
D O I：
10.1002/pol.20220086
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The photoinduced energy/electron transfer-reversible addition-fragmentation chain transfer (PET-RAFT) polymerizations of oligo(ethylene oxide) monomethyl ether methacrylate (OEOMA, also known as poly[ethylene glycol] methyl ether methacrylate, PEGMA) and isomeric methyl 2-(oligo(ethylene oxide) methyl ether)acrylate (2OEOAM) macromonomers with OEO average degree of polymerization of 22 or 45 were conducted in aqueous media to provide insight into the effect of monomer structure on grafting-through RAFT of 1,1-disubstituted acrylic macromonomers. The polymerizations of all four monomers reached nearly quantitative conversion. The longer macromonomers polymerized faster than the shorter ones within the same monomer class. The OEO side chain at the alpha (i.e., 2-) position of isomeric acrylates significantly slowed RAFT polymerization in comparison with OEO ester side chain of methacrylates.
引用
收藏
页码：1887 / 1898
页数：12
相关论文
共 50 条
  • [31] Self-Assembly of Poly(vinylpyridine-b-oligo(ethylene glycol) methyl ether methacrylate) Diblock Copolymers
    Stewart-Sloan, Charlotte R.
    Wang, Rui
    Sing, Michelle K.
    Olsen, Bradley D.
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2017, 55 (15) : 1181 - 1190
  • [32] Dynamic Properties of Self-Assembled Mono layers of Mercapto Oligo(ethylene oxide) Methyl Ether on an Oscillating Solid-Liquid Interface
    Yoshimoto, Minoru
    Honda, Keita
    Kurosawa, Shigeru
    Tanaka, Mutsuo
    JOURNAL OF PHYSICAL CHEMISTRY C, 2014, 118 (29): : 16067 - 16073
  • [33] Synthesis of water-soluble poly[oligo(ethylene glycol) methacrylate]s by living anionic polymerization of oligo(ethylene glycol) vinyl ether methacrylates
    Yamanaka, Jun
    Kayasuga, Takashi
    Ito, Mana
    Yokoyama, Hideaki
    Ishizone, Takashi
    POLYMER CHEMISTRY, 2011, 2 (08) : 1837 - 1848
  • [34] The polymerisation of oligo(ethylene glycol methyl ether) methacrylate from a multifunctional poly(ethylene imine) derived amide: a stabiliser for the synthesis and dispersion of magnetite nanoparticles
    Kleine, Aaron
    Altan, Cem L.
    Yarar, U. Ecem
    Sommerdijk, Nico A. J. M.
    Bucak, Seyda
    Holder, Simon J.
    POLYMER CHEMISTRY, 2014, 5 (02) : 524 - 534
  • [35] THE REACTIONS OF METHYL RADICALS WITH CYCLOPROPANE, ETHYLENE OXIDE, METHANOL, AND DIMETHYL ETHER
    PHIBBS, MK
    DARWENT, BD
    CANADIAN JOURNAL OF RESEARCH SECTION B-CHEMICAL SCIENCES, 1950, 28 (07): : 395 - 402
  • [36] Synthesis of Well-Defined Block Copolymer Dispersants with (2-Dimethylamino)ethyl Methacrylate and Oligo(ethylene oxide)methyl Ether Methacrylate via ATRP for Dispersing Copper Phthalocyanine Pigment
    Kim, Eunhee
    Kim, Bong-Soo
    Jung, Ki-Suk
    Kim, Jin-Goo
    Paik, Hyun-jong
    POLYMER-KOREA, 2012, 36 (01) : 104 - 110
  • [37] Poly(benzyl methacrylate)-poly[(oligo ethylene glycol) methyl ether methacrylate] triblock-copolymers as solid electrolyte for lithium batteries
    Bergfelt, Andreas
    Rubatat, Laurent
    Brandell, Daniel
    Bowden, Tim
    SOLID STATE IONICS, 2018, 321 : 55 - 61
  • [38] Comparison of reaction kinetics and gelation behaviors in atom transfer, reversible addition-fragmentation chain transfer and conventional free radical copolymerization of oligo(ethylene glycol) methyl ether methacrylate and oligo(ethylene glycol) dimethacrylate
    Yu, Qjang
    Xu, Sijia
    Zhang, Hongwen
    Ding, Yonghong
    Zhu, Shiping
    POLYMER, 2009, 50 (15) : 3488 - 3494
  • [39] Preparation and characterization of doxorubicin nanocarriers based on thermoresponsive oligo(ethylene glycol) methyl ether methacrylate polymer-drug conjugates
    Lipowska-Kur, Dania
    Szweda, Roza
    Trzebicka, Barbara
    Dworak, Andrzej
    EUROPEAN POLYMER JOURNAL, 2018, 109 : 391 - 401
  • [40] Location of a Hydrophobic Load in Poly(oligo(ethylene glycol) methyl ether methacrylate)s (PEGMAs) Dissolved in Water and Probed by Fluorescence
    Thoma, Janine L.
    Little, Hunter
    Duhamel, Jean
    LANGMUIR, 2024, 40 (11) : 5900 - 5912
12345