Dioxygen-triggered oxidative cleavage of the C-S bond towards C-N bond formation

被引：9
|
作者：
Lv, Zongchao [1 ]
Wang, Huamin [1 ]
Quan, Zhicong [1 ]
Gao, Yuan [1 ]
Lei, Aiwen [1 ,2 ]
机构：
[1] Wuhan Univ, Coll Chem & Mol Sci, Inst Adv Studies, Wuhan 430072, Hubei, Peoples R China
[2] Jiangxi Normal Univ, Natl Res Ctr Carbohydrate Synth, Nanchang 330022, Jiangxi, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 82期
基金：
中国国家自然科学基金;
关键词：
PALLADIUM-CATALYZED AMINATION; CARBON-SULFUR; COOPERATIVE CATALYSIS; EFFICIENT SYNTHESIS; METAL-COMPLEXES; ACTIVATION; FUNCTIONALIZATION; COBALT; BENZOXAZOLES; CYCLIZATION;
D O I：
10.1039/c9cc05707b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Research on the cleavage of C-C bonds has been well developed. By comparison with this, the activation of C-S bonds remains challenging. Herein, dioxygen-triggered oxidative cleavage of C-S bonds has been achieved, delivering a series of N-containing heterocyclic compounds that are frequently found in pesticides and pharmaceuticals. Additionally, the potential utility of this protocol was further demonstrated by a gram-scale experiment. Mechanistically, dioxygen plays a key role in the cleavage of C-S bonds towards C-N bond formation.
引用
收藏
页码：12332 / 12335
页数：4
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