The processes going on in silver-doped GeO2 films during air-heating were investigated by XPS, TEM, IR and UV-visible spectroscopy methods. Silver was shown to interact with the GeO2 matrix at 500-600degreesC to give silver germanate which was decomposed on further heating to form GeO2 and silver nanoparticles, 10-35nm in size. absorbing in the plasmon resonance region (lambda(max) = 415nm). The silver nanoparticles are located deep in the films and encapsulated by oxide particles. (C) 2004 Elsevier B.V. All rights reserved.
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Chinese Acad Sci, Beijing Synchrotron Radiat Facil, Inst High Energy Phys, Beijing 100049, Peoples R ChinaChinese Acad Sci, Beijing Synchrotron Radiat Facil, Inst High Energy Phys, Beijing 100049, Peoples R China
Dong, Juncai
Yao, Hurong
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Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R ChinaChinese Acad Sci, Beijing Synchrotron Radiat Facil, Inst High Energy Phys, Beijing 100049, Peoples R China
Yao, Hurong
Guo, Zhiying
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Chinese Acad Sci, Beijing Synchrotron Radiat Facil, Inst High Energy Phys, Beijing 100049, Peoples R ChinaChinese Acad Sci, Beijing Synchrotron Radiat Facil, Inst High Energy Phys, Beijing 100049, Peoples R China
Guo, Zhiying
Jia, Quanjie
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Chinese Acad Sci, Beijing Synchrotron Radiat Facil, Inst High Energy Phys, Beijing 100049, Peoples R ChinaChinese Acad Sci, Beijing Synchrotron Radiat Facil, Inst High Energy Phys, Beijing 100049, Peoples R China
Jia, Quanjie
Wang, Yan
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Chinese Acad Sci, Beijing Synchrotron Radiat Facil, Inst High Energy Phys, Beijing 100049, Peoples R China
Univ Chinese Acad Sci, Beijing 100049, Peoples R ChinaChinese Acad Sci, Beijing Synchrotron Radiat Facil, Inst High Energy Phys, Beijing 100049, Peoples R China
Wang, Yan
An, Pengfei
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Chinese Acad Sci, Beijing Synchrotron Radiat Facil, Inst High Energy Phys, Beijing 100049, Peoples R ChinaChinese Acad Sci, Beijing Synchrotron Radiat Facil, Inst High Energy Phys, Beijing 100049, Peoples R China
An, Pengfei
Gong, Yu
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Chinese Acad Sci, Beijing Synchrotron Radiat Facil, Inst High Energy Phys, Beijing 100049, Peoples R ChinaChinese Acad Sci, Beijing Synchrotron Radiat Facil, Inst High Energy Phys, Beijing 100049, Peoples R China
Gong, Yu
Liang, Yaxiang
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Chinese Acad Sci, Beijing Synchrotron Radiat Facil, Inst High Energy Phys, Beijing 100049, Peoples R ChinaChinese Acad Sci, Beijing Synchrotron Radiat Facil, Inst High Energy Phys, Beijing 100049, Peoples R China
Liang, Yaxiang
Chen, Dongliang
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Chinese Acad Sci, Beijing Synchrotron Radiat Facil, Inst High Energy Phys, Beijing 100049, Peoples R ChinaChinese Acad Sci, Beijing Synchrotron Radiat Facil, Inst High Energy Phys, Beijing 100049, Peoples R China
机构:
Univ Lyon 1, Lab Physicochim Mat Luminescents, UMR 5620, F-69622 Villeurbanne, FranceUniv Lyon 1, Lab Physicochim Mat Luminescents, UMR 5620, F-69622 Villeurbanne, France
Bressel, Lena
de Ligny, Dominique
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Univ Lyon 1, Lab Physicochim Mat Luminescents, UMR 5620, F-69622 Villeurbanne, FranceUniv Lyon 1, Lab Physicochim Mat Luminescents, UMR 5620, F-69622 Villeurbanne, France
de Ligny, Dominique
Sonneville, Camille
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Univ Lyon 1, Lab Physicochim Mat Luminescents, UMR 5620, F-69622 Villeurbanne, FranceUniv Lyon 1, Lab Physicochim Mat Luminescents, UMR 5620, F-69622 Villeurbanne, France
Sonneville, Camille
Martinez-Andrieux, Valerie
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Univ Lyon 1, Lab Physicochim Mat Luminescents, UMR 5620, F-69622 Villeurbanne, FranceUniv Lyon 1, Lab Physicochim Mat Luminescents, UMR 5620, F-69622 Villeurbanne, France
Martinez-Andrieux, Valerie
Juodkazis, Saulius
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Swinburne Univ Technol, Fac Engn & Ind Sci, Ctr Microphoton, Hawthorn, Vic 3122, AustraliaUniv Lyon 1, Lab Physicochim Mat Luminescents, UMR 5620, F-69622 Villeurbanne, France