Investigation of structural and compositional changes in silver-doped GeO2 thin films

被引:12
|
作者
Serezhkina, SDV
Tyavlovskaya, EA
Shevchenko, GP
Rakhmanov, SK
机构
[1] Belarusian State Univ, Inst Phys & Chem Res, Minsk 220080, BELARUS
[2] Natl Acad Sci Belarus, Inst Elect, Minsk 220090, BELARUS
[3] Belarusian State Univ, Minsk 220050, BELARUS
关键词
D O I
10.1016/j.jnoncrysol.2004.10.003
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The processes going on in silver-doped GeO2 films during air-heating were investigated by XPS, TEM, IR and UV-visible spectroscopy methods. Silver was shown to interact with the GeO2 matrix at 500-600degreesC to give silver germanate which was decomposed on further heating to form GeO2 and silver nanoparticles, 10-35nm in size. absorbing in the plasmon resonance region (lambda(max) = 415nm). The silver nanoparticles are located deep in the films and encapsulated by oxide particles. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:35 / 40
页数:6
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