Metal-metal (hydr)oxide heterostructures for electrocatalysis of hydrogen electrode reactions

被引：14
|
作者：
Oshchepkov, Alexandr G. [1 ]
Bonnefont, Antoine [2 ]
Savinova, Elena R. [3 ]
机构：
[1] Boreskov Inst Catalysis, Novosibirsk 630090, Russia
[2] Univ Strasbourg, Inst Chim Strasbourg, UMR 7177 CNRS, F-67070 Strasbourg, France
[3] Univ Strasbourg, Inst Chim & Proc Energie Environm & Sante, UMR 7515 CNRS, F-67087 Strasbourg, France
来源：
CURRENT OPINION IN ELECTROCHEMISTRY | 2021年 / 26卷
关键词：
Hydrogen electrode reactions in alkaline electrolytes; pH effect; Metal/metal oxide heterostructures hydrogen bonding; Interfacial water structure; EVOLUTION REACTION; OXIDATION REACTION; NICKEL HYDROXIDE; WATER; SURFACE; KINETICS; CATALYST; NI; NANOSTRUCTURES; INSIGHTS;
D O I：
10.1016/j.coelec.2020.100667
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Metal/metal (hydr)oxide heterostructures have been proposed as an efficient means to enhance the kinetics of hydrogen electrode reactions (the hydrogen evolution and the hydrogen oxidation reaction) on Pt, Ni, and other electrodes in the alkaline medium. However, the reasons for the faster electrode kinetics are still not fully understood. By considering two electrode materials, namely Pt and Ni, widely studied in hydrogen electrode reactions in alkaline media, this review brings to light differences in their pH-dependent behavior and likely different genesis of the enhancement in the presence of 3d transition metal oxides.
引用
收藏
页数：13
相关论文
共 50 条
  • [21] Resolving hydrogen atoms at metal-metal hydride interfaces
    de Graaf, Sytze
    Momand, Jamo
    Mitterbauer, Christoph
    Lazar, Sorin
    Kooi, Bart J.
    [J]. SCIENCE ADVANCES, 2020, 6 (05)
  • [22] ELECTRICAL-CONDUCTIVITY OF METAL-METAL OXIDE COMPOSITES
    KIEFFER, J
    WAGNER, JB
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1988, 135 (01) : 198 - 205
  • [23] SOME REACTIONS OF METAL CARBONYLS CONTAINING METAL-METAL BONDS - INOR
    FIELD, DS
    NEWLANDS, MJ
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1970, : 30 - &
  • [24] Metal-metal oxide pH sensors for physiological application
    O'Hare, Danny
    Parker, Kim H.
    Winlove, C. Peter
    [J]. MEDICAL ENGINEERING & PHYSICS, 2006, 28 (10) : 982 - 988
  • [25] TYPE OF ION MIGRATION IN A METAL-METAL OXIDE SYSTEM
    FLINT, O
    VARLEY, JHO
    [J]. NATURE, 1957, 179 (4551) : 145 - 146
  • [26] Metal-Metal Bonding Properties of Copper Oxide Nanoparticles
    Maeda, Takafumi
    Kobayashi, Yoshio
    Yasuda, Yusuke
    Morita, Toshiaki
    [J]. E-JOURNAL OF SURFACE SCIENCE AND NANOTECHNOLOGY, 2014, 12 : 105 - 108
  • [27] Harmonic generation from metal-oxide and metal-metal boundaries
    Scalora, M.
    Vincenti, M. A.
    de Ceglia, D.
    Akozbek, N.
    Bloemer, M. J.
    De Angelis, C.
    Haus, J. W.
    Vilaseca, R.
    Trull, J.
    Cojocaru, C.
    [J]. PHYSICAL REVIEW A, 2018, 98 (02)
  • [28] METAL-CLUSTERS AND EXTENDED METAL-METAL BONDING IN METAL-OXIDE SYSTEMS
    MCCARLEY, RE
    [J]. ACS SYMPOSIUM SERIES, 1983, 211 : 273 - 290
  • [29] Metal-metal bond formation in oxidative addition reactions.
    Fackler, JP
    Carlson, TF
    Neitling, DC
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 220 : U524 - U524
  • [30] METAL-OXIDE HETEROSTRUCTURES
    RAMESH, R
    KERAMIDAS, VG
    [J]. ANNUAL REVIEW OF MATERIALS SCIENCE, 1995, 25 : 647 - 678
12345