Chemical deposition routes to HfO2:: Real-time monitoring and film growth.

被引:0
|
作者
Forsgren, K [1 ]
Hårsta, A [1 ]
Aarik, J [1 ]
Aidla, A [1 ]
机构
[1] Univ Uppsala, Angstrom Lab, Dept Chem Mat, SE-75121 Uppsala, Sweden
关键词
D O I
暂无
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This study describes thin film deposition of HfO2 by CVD and ALCVD using HfI4 as the metal precursor for the first time. The layer by layer growth was also studied in real time with a Quartz Crystal Microbalance (QCM). Monoclinic HfO2 was deposited on MgO and poly-Si substrates in a wide temperature range, and the choice of substrate was found to have a strong influence on the orientation of the films. In ALCVD, the deposition rate was independent of the growth temperature, whereas in CVD, an exponential rate increase was observed.
引用
收藏
页码:152 / 159
页数:8
相关论文
共 50 条
  • [11] Inhomogeneous HfO2 layer growth at atomic layer deposition
    Kasikov, Aarne
    Tarre, Aivar
    Vinuesa, Guillermo
    JOURNAL OF ELECTRICAL ENGINEERING-ELEKTROTECHNICKY CASOPIS, 2023, 74 (04): : 246 - 255
  • [12] Hafnium nitrate precursor synthesis and HfO2 thin film deposition
    Zhuang, WW
    Conley, JF
    Ono, Y
    Evans, DR
    Solanki, R
    INTEGRATED FERROELECTRICS, 2002, 48 : 3 - 12
  • [13] Real-time monitoring of nanoparticle film growth at high deposition rate with optical spectroscopy of plasmon resonances
    Grachev, Sergey
    de Grazia, Marco
    Barthel, Etienne
    Sondergard, Elin
    Lazzari, Remi
    JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2013, 46 (37)
  • [14] Using tetrakis-diethylamido-hafnium for HfO2 thin-film growth in low-pressure chemical vapor deposition
    Ohshita, Y
    Ogura, A
    Hoshino, A
    Hiiro, S
    Suzuki, T
    Machida, H
    THIN SOLID FILMS, 2002, 406 (1-2) : 215 - 218
  • [15] Real-time monitoring of 2D semiconductor film growth with optical spectroscopy
    Wei, Yaxu
    Shen, Wanfu
    Roth, Dietmar
    Wu, Sen
    Hu, Chunguang
    Li, Yanning
    Hu, Xiaotang
    Hohage, Michael
    Bauer, Peter
    Sun, Lidong
    NANOTECHNOLOGY, 2017, 28 (46)
  • [16] Obvious ferroelectricity in undoped HfO2 films by chemical solution deposition
    Chen, Haiyan
    Chen, Yonghong
    Tang, Lin
    Luo, Hang
    Zhou, Kechao
    Yuan, Xi
    Zhang, Dou
    JOURNAL OF MATERIALS CHEMISTRY C, 2020, 8 (08) : 2820 - 2826
  • [17] Effect of film growth thickness on the refractive index and crystallization of HfO2 film
    Hu, Jianping
    Wang, Jian
    Wei, Yaowei
    Wu, Qian
    Zhang, Fei
    Xu, Qiao
    CERAMICS INTERNATIONAL, 2021, 47 (23) : 33751 - 33757
  • [18] Interfacial chemical structure of HfO2/Si film fabricated by sputtering
    Jiang, Ran
    Xie, Erqing
    Wang, Zhenfang
    APPLIED PHYSICS LETTERS, 2006, 89 (14)
  • [19] REAL-TIME MONITORING OF A SURFACE-REACTION IN GERMANIUM FILM GROWTH
    ERES, D
    SHARP, JW
    APPLIED PHYSICS LETTERS, 1992, 60 (22) : 2764 - 2766
  • [20] Initial growth of interfacial oxide during deposition of HfO2 on silicon
    Choi, K
    Temkin, H
    Harris, H
    Gangopadhyay, S
    Xie, L
    White, M
    APPLIED PHYSICS LETTERS, 2004, 85 (02) : 215 - 217