This study describes thin film deposition of HfO2 by CVD and ALCVD using HfI4 as the metal precursor for the first time. The layer by layer growth was also studied in real time with a Quartz Crystal Microbalance (QCM). Monoclinic HfO2 was deposited on MgO and poly-Si substrates in a wide temperature range, and the choice of substrate was found to have a strong influence on the orientation of the films. In ALCVD, the deposition rate was independent of the growth temperature, whereas in CVD, an exponential rate increase was observed.
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Lab Mixte CNRS St Gobain Surface Verre & Interfac, F-93303 Aubervilliers, FranceLab Mixte CNRS St Gobain Surface Verre & Interfac, F-93303 Aubervilliers, France
Grachev, Sergey
de Grazia, Marco
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Lab Mixte CNRS St Gobain Surface Verre & Interfac, F-93303 Aubervilliers, FranceLab Mixte CNRS St Gobain Surface Verre & Interfac, F-93303 Aubervilliers, France
de Grazia, Marco
Barthel, Etienne
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Lab Mixte CNRS St Gobain Surface Verre & Interfac, F-93303 Aubervilliers, FranceLab Mixte CNRS St Gobain Surface Verre & Interfac, F-93303 Aubervilliers, France
Barthel, Etienne
Sondergard, Elin
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Lab Mixte CNRS St Gobain Surface Verre & Interfac, F-93303 Aubervilliers, FranceLab Mixte CNRS St Gobain Surface Verre & Interfac, F-93303 Aubervilliers, France
Sondergard, Elin
Lazzari, Remi
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Univ Paris 06, CNRS, UMR 7588, Inst NanoSci Paris, F-75252 Paris 05, FranceLab Mixte CNRS St Gobain Surface Verre & Interfac, F-93303 Aubervilliers, France
机构:
Cent South Univ, State Key Lab Powder Met, Changsha 410083, Peoples R ChinaCent South Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China
Chen, Haiyan
Chen, Yonghong
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Cent South Univ, State Key Lab Powder Met, Changsha 410083, Peoples R ChinaCent South Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China
Chen, Yonghong
Tang, Lin
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Cent South Univ, State Key Lab Powder Met, Changsha 410083, Peoples R ChinaCent South Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China
Tang, Lin
Luo, Hang
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Cent South Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China
Cent South Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R ChinaCent South Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China
Luo, Hang
Zhou, Kechao
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Cent South Univ, State Key Lab Powder Met, Changsha 410083, Peoples R ChinaCent South Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China
Zhou, Kechao
Yuan, Xi
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Cent South Univ, State Key Lab Powder Met, Changsha 410083, Peoples R ChinaCent South Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China
Yuan, Xi
Zhang, Dou
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Cent South Univ, State Key Lab Powder Met, Changsha 410083, Peoples R ChinaCent South Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China