Factors Affecting Hydrogen Adsorption in Metal-Organic Frameworks: A Short Review

被引：38
|
作者：
Zelenak, Vladimir [1 ]
Saldan, Ivan [1 ,2 ]
机构：
[1] Pavol Jozef Safarik Univ Kosice, Fac Sci, Dept Inorgan Chem, Moyzesova 11, Kosice 04154, Slovakia
[2] Ivan Franko Natl Univ Lviv, Fac Chem, Dept Phys & Colloid Chem, Kyryla & Mefodia 6, UA-79005 Lvov, Ukraine
来源：
NANOMATERIALS | 2021年 / 11卷 / 07期
关键词：
adsorption; hydrogen; MOF; nanoconfinement; metal hydrides; POROUS COORDINATION POLYMERS; HIGH-SURFACE-AREA; GAS-ADSORPTION; AT-MOF; POTENTIAL ADSORBENTS; NANOPOROUS POLYMERS; SORPTION PROPERTIES; ULTRAHIGH POROSITY; CATALYTIC-ACTIVITY; HIGH-PERFORMANCE;
D O I：
10.3390/nano11071638
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metal-organic frameworks (MOFs) have significant potential for hydrogen storage. The main benefit of MOFs is their reversible and high-rate hydrogen adsorption process, whereas their biggest disadvantage is related to their operation at very low temperatures. In this study, we describe selected examples of MOF structures studied for hydrogen adsorption and different factors affecting hydrogen adsorption in MOFs. Approaches to improving hydrogen uptake are reviewed, including surface area and pore volume, in addition to the value of isosteric enthalpy of hydrogen adsorption. Nanoconfinement of metal hydrides inside MOFs is proposed as a new approach to hydrogen storage. Conclusions regarding MOFs with incorporated metal nanoparticles, which may be used as nanoscaffolds and/or H-2 sorbents, are summarized as prospects for the near future.
引用
收藏
页数：33
相关论文
共 50 条
  • [41] Unusual Adsorption Behavior on Metal-Organic Frameworks
    Fairen-Jimenez, David
    Seaton, Nigel A.
    Duren, Tina
    [J]. LANGMUIR, 2010, 26 (18) : 14694 - 14699
  • [42] Water Stability and Adsorption in Metal-Organic Frameworks
    Burtch, Nicholas C.
    Jasuja, Himanshu
    Walton, Krista S.
    [J]. CHEMICAL REVIEWS, 2014, 114 (20) : 10575 - 10612
  • [43] Enantioselective adsorption in zeolites and metal-organic frameworks
    Bueno-Perez, Rocio
    Martin-Calvo, Ana
    Gomez-Alvarez, Paula
    Gutierrez-Sevillano, Juan-Jose
    Merkling, Patrick
    Vlugt, Thijs
    van Erp, Titus S.
    Dubbeldam, David
    Calero, Sofia
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
  • [44] Metal-organic frameworks for water vapor adsorption
    Shi, Le
    Kirlikovali, Kent O.
    Chen, Zhijie
    Farha, Omar K.
    [J]. CHEM, 2024, 10 (02): : 484 - 503
  • [45] Shaping of Metal-Organic Frameworks: A Review
    Wang, Zhe
    Liu, Liying
    Li, Zhuo
    Goyal, Nitin
    Du, Tao
    He, Jiaxin
    Li, Gang Kevin
    [J]. ENERGY & FUELS, 2022, 36 (06) : 2927 - 2944
  • [46] Review on Flexible Metal-Organic Frameworks
    Kaur, Jagdeep
    Kaur, Gurmeet
    [J]. CHEMISTRYSELECT, 2021, 6 (32): : 8227 - 8243
  • [47] Hydrogen adsorption in metal organic frameworks by hydrogen spillover
    Lin, Kuen-Song
    Adhikari, Abhijit Krishna
    Chang, Kai-Che
    Tu, Mu-Ting
    Lu, Wei
    [J]. CATALYSIS TODAY, 2011, 164 (01) : 23 - 27
  • [48] Metal-organic frameworks in separations: A review
    Firooz, Sepideh Khaki
    Armstrong, Daniel W.
    [J]. ANALYTICA CHIMICA ACTA, 2022, 1234
  • [49] Metal-organic frameworks for pesticidal persistent organic pollutants detection and adsorption - A mini review
    Wagner, Michal
    Lin, Kun-Yi Andrew
    Oh, Wen-Da
    Lisak, Grzegorz
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2021, 413
  • [50] Nanoporous metal-organic frameworks for hydrogen storage
    Ma, Shengqian
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 246
12345