Synthesis, characterization and optical properties of new tetrafluorenyl-porphyrins peripherally functionalized with conjugated 2-fluorenone groups

被引：4
|
作者：
Zhang, Xu [1 ]
Sun, Zhipeng [1 ]
Richy, Nicolas [1 ]
Mongin, Olivier [1 ]
Paul, Frederic [1 ]
Blanchard-Desce, Mireille [2 ]
Paul-Roth, Christine O. [1 ]
机构：
[1] Univ Rennes, INSA Rennes, CNRS, ISCR Inst Sci Chim Rennes UMR 6226, F-35000 Rennes, France
[2] Univ Bordeaux, Inst Sci Mol CNRS UMR 5255, F-33405 Talence, France
来源：
NEW JOURNAL OF CHEMISTRY | 2021年 / 45卷 / 33期
关键词：
SINGLET OXYGEN; PHOTODYNAMIC THERAPY; ENERGY-TRANSFER; CROSS-SECTIONS; FLUORENYL; PHOTOSENSITIZERS; TETRAPHENYLPORPHYRINS; PHTHALOCYANINES; ARMS;
D O I：
10.1039/d1nj01410b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of new meso-tetrafluorenylporphyrins peripherally functionalized with various 2-ethynyl fluorenyl and/or 2-ethynyl fluorenonyl arms is presented. The impact of these fluorenone units on their linear and nonlinear optical properties is also investigated. Thus, two-photon absorption and singlet oxygen photosensitising properties are evaluated. Improvement of these properties relative to their analogues featuring non-oxidized fluorenyl terminal groups, which make the molecules presented quite appealing for combined 2-photon-based photodynamic therapy (PDT) and imaging, is then briefly discussed.
引用
收藏
页码：15053 / 15062
页数：10
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