Outer-sphere association constants of cobalt(III) ammines and acidoammines with phosphorus(V) in aqueous solution

被引：0

作者：

Zorina, NV ^{[1
]}

Stupko, TV ^{[1
]}

Pashkov, GL ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Chem & Chem Technol, Siberian Div, Krasnoyarsk, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2000年 / 45卷 / 11期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electronic spectra of aqueous solutions in the range of 230-350 nm were measured to study the association of cations [CO(NH3)(5)C2O4](+) [CO(NH3)(5)SO4](+), [CO(NH3)(5)OH](2+), [Co(NH3)(5)NO2](2+), [Co(NH3)(6)](3+), and [Coen(3)](3+) with H2PO4-, HPO42-, PO43-, P3O93-, P2O74-, and P4O124- anions. The first association constants beta (0)(1) of the specified cations with the specified anions at I --> 0 and 25 degreesC were determined. An equation log beta (0)(1) = AZ(+) + B, where Z(+) is the charge of a cobalt(III) complex and A and B are constants, quantifies all of the association constants found.

引用

页码：1767 / 1770

页数：4

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