Synthetic access to arsenic-containing phosphatidylcholines

被引：13
|
作者：
Guttenberger, Nikolaus [1 ]
Glabonjat, Ronald A. [1 ]
Tassoti, Sebastian [1 ]
Francesconi, Kevin A. [1 ]
机构：
[1] Karl Franzens Univ Graz, NAWI Graz, Inst Chem, Univ Pl 1, A-8010 Graz, Austria
来源：
TETRAHEDRON LETTERS | 2017年 / 58卷 / 27期
基金：
奥地利科学基金会;
关键词：
Arsenic; Arsenolipid; AsPC; Natural product; CONTAINING HYDROCARBONS; BROWN ALGA; ARSENOLIPIDS; PHOSPHOLIPIDS; OIL; 5-DEOXY-5-DIMETHYLARSINYL-BETA-D-RIBOSIDE; IDENTIFICATION; ACYLATION;
D O I：
10.1016/j.tetlet.2017.05.065
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We wish to disclose the first synthesis of 1-0-hexadecanoy1-2-0((15-(dimethylarsinoyl)pentadecanoyl) oxy)-sn-glycero-3-phosphocholine, which belongs to the group of arsenic -containing phosphatidylcholines (AsPCs), recently discovered in herring caviar. The synthesized product will serve as a model compound to study biological and toxicological properties of arsenolipids in food. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2651 / 2653
页数：3
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