Reactions of rhodium carbonyl clusters with heterobidentate ligands. Synthesis and structural characterization of the Rh6(CO)15[(C6H5)2PC6H4N(CH3)2] and {Rh6(CO)15[(C6H5)2PC6H4NH(CH3)2]}[GaX4] cluster compounds

被引：4

作者：

Gracheva, E. V. ^{[1
]}

Linti, G. ^{[2
]}

机构：

[1] St Petersburg State Univ, St Petersburg 198504, Russia

[2] Univ Heidelberg, Heidelberg, Germany

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2010年 / 80卷 / 03期

关键词：

DYNAMIC-BEHAVIOR; DISUBSTITUTED-DERIVATIVES; RH-6(CO)(15)L CLUSTERS; CRYSTAL-STRUCTURES; PHOSPHINE-LIGANDS; GACP-ASTERISK; REACTIVITY; KINETICS;

D O I：

10.1134/S1070363210030072

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of heterobidentate 4-(dimethylamino)phenyldiphenylphosphine with labile cluster Rh-6(CO)(15)(NCMe) yielding a new monosubstituted cluster Rh-6(CO)(15)(Ph2PC6H4NMe2) was described. The reactions of the resulting cluster with GaX3 compounds were studied. The structure of all obtained compounds was completely characterized both in a solid phase and in a solution by X-ray diffraction analysis, mass spectrometry, and IR and polynuclear NMR spectroscopy.

引用

页码：414 / 422

页数：9

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