Combustion-mediated synthesis of hollow carbon nanospheres for high-performance cathode material in lithium-sulfur battery

Hollow carbon nanospheres as potential cathode materials for lithium-sulfur (Li-S) batteries were successfully synthesized using a metathesis reaction between sodium azide and halogen polymer. The reaction was driven by thermal heat from the exothermic recombination of Na+ and Cl- (or F-) ions into NaCl (or NaF) salts. The result was an increase of the overall system temperature up to 1320-1750 degrees C followed by the simultaneous formation of sodium halide-carbon coreeshell nanoparticles. Therefore, hollow carbon nanospheres with diameter and shell thickness of similar to 50-500 nm and similar to 10-50 nm, respectively, were produced after water washing of the reaction product. The composite cathode materials for Li-S batteries were manufactured by infiltrating sulfur into the hollow core of nanospheres. The electrochemical cycling showed discharge capacity of similar to 700 mAh g(-1) (after 100 cycles) at 0.5 degrees C current rate which is more than similar to 2.4 times larger than that for the sulfur/carbon black composites prepared by the same technique. The enhancement of battery performance was attributed to the well-organized and unique 3D structure of hollow carbon, enabling better utilization of sulfur. (C) 2016 Elsevier Ltd. All rights reserved.