W-ZrC composites without residual WC have been prepared for the first time by reactive infiltration at 1300 degrees C for 1 h in vacuum using a molten Zr2Cu alloy and a newly designed partially-carburized W powder as raw materials. The as -synthesized composites consist of two major phases of W and ZrC, in which the content of W is 65 vol%. The reaction time needed to produce a fully densified W-ZrC bulk ceramic is distinctly shortened by this means, as contrasted with conventional WC/W or WC preforms. The microstructural evolution during reactive melt infiltration is investigated to obtain a better understanding of reaction mechanisms and mechanical properties of the W-ZrC composites derived by infiltrating Zr2Cu alloy into partially carburized W preforms. The flexural strength, Young's modulus and fracture toughness for the W-ZrC composite are 554 MPa, 339 GPa and 9.7 MPaln(1/2,) respectively.
机构:
Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
Chinese Acad Sci, Shanghai Inst Ceram, Struct Ceram & Composites Engn Res Ctr, Shanghai 200050, Peoples R China
Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R ChinaChinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
Chen, Xiaowu
Dong, Shaoming
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Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
Chinese Acad Sci, Shanghai Inst Ceram, Struct Ceram & Composites Engn Res Ctr, Shanghai 200050, Peoples R ChinaChinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
Dong, Shaoming
Kan, Yanmei
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Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
Chinese Acad Sci, Shanghai Inst Ceram, Struct Ceram & Composites Engn Res Ctr, Shanghai 200050, Peoples R ChinaChinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
Kan, Yanmei
Jin, Xihai
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Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
Chinese Acad Sci, Shanghai Inst Ceram, Struct Ceram & Composites Engn Res Ctr, Shanghai 200050, Peoples R ChinaChinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
Jin, Xihai
Zhou, Haijun
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Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
Chinese Acad Sci, Shanghai Inst Ceram, Struct Ceram & Composites Engn Res Ctr, Shanghai 200050, Peoples R ChinaChinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
Zhou, Haijun
Ni, Dewei
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Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
Chinese Acad Sci, Shanghai Inst Ceram, Struct Ceram & Composites Engn Res Ctr, Shanghai 200050, Peoples R ChinaChinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
Ni, Dewei
Wang, Dengke
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Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
Chinese Acad Sci, Shanghai Inst Ceram, Struct Ceram & Composites Engn Res Ctr, Shanghai 200050, Peoples R China
Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R ChinaChinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
机构:
Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R ChinaCent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China
Wu, Huang
Yi, Maozhong
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Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R ChinaCent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China
Yi, Maozhong
Ge, Yicheng
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Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R ChinaCent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China
Ge, Yicheng
Peng, Ke
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Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R ChinaCent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China
Peng, Ke
Ran, Liping
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Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R ChinaCent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China