Non-planar structures of Et3N and Pri3 N:: a contradiction between the x-ray, and NMR and electron diffraction data for Pri3N

被引：35
|
作者：
Boese, R
Bläser, D
Antipin, MY
Chaplinski, V
de Meijere, A
机构：
[1] Univ Essen Gesamthsch, Inst Anorgan Chem, D-45117 Essen, Germany
[2] Russian Acad Sci, Inst Organoelement Cpds, Moscow 117813, Russia
[3] Univ Gottingen, Inst Organ Chem, D-37077 Gottingen, Germany
来源：
CHEMICAL COMMUNICATIONS | 1998年 / 07期
关键词：
D O I：
10.1039/a708399h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystal structures of Et3N and (Pr3N)-N-i were determined by X-ray analysis using the in situ crystallization technique for single crystal growth on the diffractometer; both have a pyramidal configuration of the nitrogen atom, even (Pr3N)-N-i, which was considered to be planar in accord with electron diffraction and NMR data.
引用
收藏
页码：781 / 782
页数：2
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