Influence of oxygen on semi-transparent organic solar cells with gas permeable electrodes

被引:109
|
作者
Seemann, Andrea [1 ]
Egelhaaf, H. -J. [1 ]
Brabec, Christoph J. [1 ]
Hauch, Jens A. [1 ]
机构
[1] Konarka Technol GmbH, D-90443 Nurnberg, Germany
关键词
Organic solar cells; Degradation; Oxygen; Transparent electrode; FIELD-EFFECT TRANSISTORS; C-60; THIN-FILMS; IMPEDANCE SPECTROSCOPY; C-70; FILMS; PHOTOCONDUCTIVITY; DEGRADATION; PHOTOVOLTAICS; STABILITY; STATES;
D O I
10.1016/j.orgel.2009.08.001
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Semi-transparent P3HT:PCBM (poly(3-hexylthiophene):[6,6]-phenyl C61 butyric acid methyl ester) solar cells with high conductivity PEDOT:PSS (poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)) top electrodes are used to study degradation. Due to the gas permeability of this type of electrode, the simultaneous exposure to oxygen and light leads to a strong decrease of the short circuit current on the timescale of minutes. The losses are not due to a change in the conductivity of the PEDOT:PSS layer, and the short circuit current can be partially recovered by a heating step, indicating that the observed degradation is taking place in the photo-active layer of the cell. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:1424 / 1428
页数:5
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