Total synthesis of jerangolid D

被引：70
|
作者：
Pospisil, Jiri [1 ]
Marko, Istvan E. [1 ]
机构：
[1] Catholic Univ Louvain, Dept Chim, B-1348 Louvain, Belgium
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 12期
关键词：
D O I：
10.1021/ja0691728
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A short and convergent synthesis of jerangolid D is described. As key steps, a Blaise reaction is employed to construct the lactone ring, a diastereoselective multicomponent Sakurai condensation leads to the dihydropyran ring, and the skipped diene is assembled using a modified Julia olefination.
引用
收藏
页码：3516 / +
页数：3
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