Chiral Ligands Derived from Monoterpenes: Application in the Synthesis of Optically Pure Secondary Alcohols via Asymmetric Catalysis

被引：55

作者：

Ibn El Alami, Mohammed Samir ^{[1
]}

Amin El Amrani, Mohamed ^{[1
]}

Agbossou-Niedercorn, Francine ^{[2
]}

Suisse, Isabelle ^{[2
]}

Mortreux, Andre ^{[2
]}

机构：

[1] Univ Abdelmalek Essaadi, Lab Chim Organ Appl, Fac Sci, Tetouan, Morocco

[2] Univ Lille Nord France, UMR CNRS 8181, UCCS, ENSCL, F-59652 Villeneuve Dascq, France

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2015年 / 21卷 / 04期

关键词：

alcohols; asymmetric catalysis; chiral ligands; natural product synthesis; terpenes; HIGHLY ENANTIOSELECTIVE ADDITION; TRANSFER HYDROGENATION; BORANE REDUCTION; PROCHIRAL KETONES; AMINO-ALCOHOLS; N-OXIDES; STEREOSELECTIVE-SYNTHESIS; TERPENE AUXILIARIES; CARBONYL-COMPOUNDS; ALPHA-PINENE;

D O I：

10.1002/chem.201404303

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The preparation of optically pure secondary alcohols in the presence of catalysts based on chiral ligands derived from monoterpenes, such as pinenes, limonenes and carenes, is reviewed. A wide variety of these ligands has been synthesized and used in several catalytic reactions, including hydrogen transfer, C-C bond formation via addition of organozinc compounds to aldehydes, hydrosilylation, and oxazaborolidine reduction, leading to high activities and enantioselectivities.

引用

页码：1398 / 1413

页数：16

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