Development of new radical reactions: Skeletal rearrangement via alkoxy radicals and asymmetric radical cyclization

被引：0

作者：

Nishida, A ^{[1
]}

Nishida, M ^{[1
]}

机构：

[1] HOKKAIDO UNIV,FAC PHARMACEUT SCI,SAPPORO,HOKKAIDO 060,JAPAN

来源：

REVIEWS ON HETEROATOM CHEMISTRY | 1997年 / 16卷

关键词：

alkoxy radical; beta-cleavage; beta-diastereoselective radical cyclization; 8-phenylmenthyl ester; enantioselective radical cyclization; Lewis acid;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The generation and reaction of alkoxy radicals are discussed. The alkoxy radicals were useful for the radical transposition via skeletal rearrangement. Inter- and intramolecular beta-Diastereoselective radical additions to chiral alpha,beta-unsaturated esters were developed. The presence of a Lewis acid was necessary for high selectivity.

引用

页码：287 / 311

页数：25

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