Development of new radical reactions: Skeletal rearrangement via alkoxy radicals and asymmetric radical cyclization

被引：0
|
作者：
Nishida, A [1 ]
Nishida, M [1 ]
机构：
[1] HOKKAIDO UNIV,FAC PHARMACEUT SCI,SAPPORO,HOKKAIDO 060,JAPAN
来源：
REVIEWS ON HETEROATOM CHEMISTRY | 1997年 / 16卷
关键词：
alkoxy radical; beta-cleavage; beta-diastereoselective radical cyclization; 8-phenylmenthyl ester; enantioselective radical cyclization; Lewis acid;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The generation and reaction of alkoxy radicals are discussed. The alkoxy radicals were useful for the radical transposition via skeletal rearrangement. Inter- and intramolecular beta-Diastereoselective radical additions to chiral alpha,beta-unsaturated esters were developed. The presence of a Lewis acid was necessary for high selectivity.
引用
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页码：287 / 311
页数：25
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