Stereospecific cascade cyclization reaction with the formation of tetracyclic hexacoordinated phosphorus derivatives

被引:5
|
作者
Pudovik, Mikhail A. [1 ]
Kibardina, Lyudmila K. [1 ]
Terent'eva, Svetlana A. [1 ]
Burilov, Alexander R. [1 ]
Kataeva, Olga N. [1 ]
Chmutova, Galina A. [1 ]
Latypov, Shamil K. [1 ]
Sinyashin, Oleg G. [1 ]
Alfonsov, Vladimir A. [1 ]
机构
[1] Russian Acad Sci, AE Arbuzov Organ & Phys Chem Inst, Kazan Sci Ctr, Kazan 420088, Russia
基金
俄罗斯基础研究基金会;
关键词
MOLECULAR-STRUCTURE; FLUORINE CHEMISTRY; PRODUCT; CRYSTAL;
D O I
10.1016/j.mencom.2010.06.015
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new type of stereospecific cascade cyclization was observed in the phosphorylation reaction of N,N'-bis(salicylidene)ethylenediimine with alkylenechlorophosphites, which resulted in the formation of tetracyclic hexacoordinated phosphorus derivatives containing the P-C-N fragment with a chiral carbon atom in the alpha-position to phosphorus.
引用
收藏
页码:226 / 228
页数:3
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