Enantiopure 3-amido or 3,3′-bisamido substituted 1,1′-bi-2-naphthols by anionic Fries rearrangements

被引:22
|
作者
Dennis, MR [1 ]
Woodward, S [1 ]
机构
[1] Univ Hull, Dept Chem, Kingston Upon Hull HU6 7RX, Yorks, England
关键词
D O I
10.1039/a708436f
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Mono- or di-carbamates of 1,1'-bi-2-naphthol ortholithiate with (BuLi)-Li-s-TMEDA, The resulting anions may either be captured by MeI or allowed to undergo anionic Fries rearrangement, Thus generalised two-step routes to mono-and di-(3-alkyl) or -(3-amido) substituted 2,2'-binapthols is demonstrated.
引用
收藏
页码:1081 / 1085
页数:5
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