Hydrothermal Synthesis and Thermoelectric Properties of New Oxides (Ca0.85-xNdxOH)1.16CoO2

被引：0

作者：

Pei Jian ^{[1
]}

Chen Gang ^{[1
]}

Wang Qun ^{[1
]}

Jin Ren-Cheng ^{[1
]}

机构：

[1] Harbin Inst Technol, Dept Chem, Harbin 150001, Peoples R China

来源：

JOURNAL OF INORGANIC MATERIALS | 2010年 / 25卷 / 06期

基金：

中国国家自然科学基金;

关键词：

hydrothermal synthesis; layered cobalt oxide; thermoelectric properties; CA3CO4O9+DELTA;

D O I：

10.3724/SP.J.1077.2010.00669

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Plate-like particles of (Ca0.85OH)(1.16)CoO2 were prepared in which Nd was partially substituted for Ca to improve the thermoelectric performance. The values of Seebeck coefficient of as-synthesized oxides are all positive, showing that these oxides are p-type materials. The electrical conductivity initially decreases then increases with increasing Nd-doped amount, which is the coeffect of carrier concentration and carrier mobility. The Seebeck coefficient increases with the increasing Nd-doped amount below 473K. The power factor reaches 7.06 x 10(-5) W/(m.K-2) at 573K for (Ca0.75Nd0.1OH)(1.16)CoO2.

引用

页码：669 / 672

页数：4

共 14 条

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