Synthesis of β-iminoaminate zirconium complexes and their application in ethylene polymerization

被引：38
|
作者：
Jin, X
Novak, BM [1 ]
机构：
[1] N Carolina State Univ, Dept Chem, Raleigh, NC 27695 USA
[2] Univ Massachusetts, Polymer Sci & Engn Dept, Amherst, MA 01003 USA
来源：
MACROMOLECULES | 2000年 / 33卷 / 17期
关键词：
D O I：
10.1021/ma0000428
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The synthesis and polymerization activity of a new class of homogeneous catalysts based on the non-Cp ligands, β-iminoamines (β-IAMs). The successful zirconium catalyst series includes β-iminoamine compounds possessing different aromatic aliphatic substituents. When activated by methylaluminoxane (MAO), it was found out that the β-iminoaminate zirconium complexes are highly active catalyts for the polymerization of ethylene.
引用
收藏
页码：6205 / 6207
页数：3
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