Insertion of O2 into a Pd(I)-Pd(I) dimer and subsequent C-O bond formation by activation of a C-H bond

被引：41

作者：

Durà-Vilà, V ^{[1
]}

Mingos, DMP ^{[1
]}

Vilar, R ^{[1
]}

White, AJP ^{[1
]}

Williams, DJ ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 16期

关键词：

D O I：

10.1039/b004537n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction between O-2 and the dimer [Pd-2(mu-Br)(2)(PBu3t)(2)] leads to the formation of the novel dimeric compound[Pd(mu-OCH2{CMe2}PBu2t)Br](2) by coordination of O-2 to the original palladium dimer and further formation of two C-O bonds by intramolecular activation of C-H bonds.

引用

页码：1525 / 1526

页数：2

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