The synthesis and thermal phase transition behavior of poly(N-isopropylacrylamide)-b-poly(ethylene oxide)

被引:23
|
作者
Lee, KK
Jung, JC
Jhon, MS
机构
[1] Korea Adv Inst Sci & Technol, Ctr Mol Sci, Taejon 305701, South Korea
[2] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305701, South Korea
关键词
D O I
10.1007/s002890050276
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
By using the redox reaction between Ce(IV) and terminal -CH(2)OH groups of polyethylene oxide(PEO), block copolymers composed of poly(N-isopropylacrylamide)(PNiPAAm) and poly(ethylene oxide) was prepared. The aqueous solution of the block copolymers exhibited thermal phase transition and the phase transition temperature of these block copolymers became higher than the PNiPAAm homopolymer.
引用
收藏
页码:455 / 460
页数:6
相关论文
共 50 条
  • [41] Thermal Characterizations of Semi-Interpenetrating Polymer Networks Composed of Poly(ethylene oxide) and Poly(N-isopropylacrylamide)
    Kim, Seon Jeona
    Lee, Chang Kee
    Lee, Young Moo
    Lee, Kyu Back
    Park, Yong Doo
    Kim, Sun I.
    Journal of Applied Polymer Science, 2003, 90 (14): : 3922 - 3927
  • [42] Grafting of poly(N-isopropylacrylamide) with poly(ethylene oxide) under various reaction conditions
    Virtanen, J
    Baron, C
    Tenhu, H
    MACROMOLECULES, 2000, 33 (02) : 336 - 341
  • [43] Aqueous Solutions of Poly(ethylene oxide)-Poly(N-isopropylacrylamide): Thermosensitive Behavior and Distinct Multiple Assembly Processes
    Wang, Qiuwen
    Tang, Hui
    Wu, Peiyi
    LANGMUIR, 2015, 31 (23) : 6497 - 6506
  • [44] Thermal characterizations of semi-interpenetrating polymer networks composed of poly(ethylene oxide) and poly(N-isopropylacrylamide)
    Kim, SJ
    Lee, CK
    Lee, YM
    Lee, KB
    Park, YD
    Kim, SI
    JOURNAL OF APPLIED POLYMER SCIENCE, 2003, 90 (14) : 3922 - 3927
  • [45] Temperature-sensitive behaviour of poly(glycidol)-b-poly(N-isopropylacrylamide) block copolymers
    Sebastian Mendrek
    Aleksandra Mendrek
    Hans-Juergen Adler
    Andrzej Dworak
    Dirk Kuckling
    Colloid and Polymer Science, 2010, 288 : 777 - 786
  • [46] Thermosensitive poly(N-isopropylacrylamide)-b-poly(ε-caprolactone) nanoparticles for efficient drug delivery system
    Choi, Changyong
    Chae, Su Young
    Nah, Jae-Won
    POLYMER, 2006, 47 (13) : 4571 - 4580
  • [47] Temperature-sensitive behaviour of poly(glycidol)-b-poly(N-isopropylacrylamide) block copolymers
    Mendrek, Sebastian
    Mendrek, Aleksandra
    Adler, Hans-Juergen
    Dworak, Andrzej
    Kuckling, Dirk
    COLLOID AND POLYMER SCIENCE, 2010, 288 (07) : 777 - 786
  • [48] Synthesis and self-assembly of poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide)-g-poly(acrylic acid) gels
    Bromberg, L
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2001, 40 (11) : 2437 - 2444
  • [49] Synthesis and crystallizability of poly(ethylene glycol)-b-poly(ε-caprolactone)-b-poly(ethylene glycol)
    Wang, Pei
    Liu, Lian
    Qu, Chao
    Wei, Zhiyong
    Qi, Min
    JOURNAL OF CONTROLLED RELEASE, 2011, 152 : E240 - E242
  • [50] Understanding drug release from poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide) gels
    Anderson, BC
    Pandit, NK
    Mallapragada, SK
    JOURNAL OF CONTROLLED RELEASE, 2001, 70 (1-2) : 157 - 167