Schiff-base coordination complexes with plutonium(iv) and cerium(iv)

被引：30
|
作者：
Klamm, Bonnie E. [1 ]
Windorff, Cory J. [1 ]
Marsh, Matthew L. [1 ]
Meeker, David S. [1 ]
Albrecht-Schmitt, Thomas E. [1 ]
机构：
[1] Florida State Univ, Dept Chem & Biochem, 95 Chieftan Way,RM 118 DLC, Tallahassee, FL 32306 USA
来源：
CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 62期
关键词：
LANTHANIDE; CHEMISTRY; CE(IV); CE;
D O I：
10.1039/c8cc03571g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
PuL2 and CeL2 (L = N,N-bis[(4,4-diethylamino)salicylidene]-1,2-phenylenediamine) have been synthesized, and characterized by single crystal X-ray diffraction, UV/vis/NIR spectroscopy, and cyclic voltammetry. These studies reveal the enhanced stabilization of Pu(iv) versus Ce(iv) with this Schiff base, and quasi-reversible redox behaviour only with the plutonium complex.
引用
收藏
页码：8634 / 8636
页数：3
相关论文
共 50 条
12345