Schiff-base coordination complexes with plutonium(iv) and cerium(iv)

被引：30

作者：

Klamm, Bonnie E. ^{[1
]}

Windorff, Cory J. ^{[1
]}

Marsh, Matthew L. ^{[1
]}

Meeker, David S. ^{[1
]}

Albrecht-Schmitt, Thomas E. ^{[1
]}

机构：

[1] Florida State Univ, Dept Chem & Biochem, 95 Chieftan Way,RM 118 DLC, Tallahassee, FL 32306 USA

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 62期

关键词：

LANTHANIDE; CHEMISTRY; CE(IV); CE;

D O I：

10.1039/c8cc03571g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

PuL2 and CeL2 (L = N,N-bis[(4,4-diethylamino)salicylidene]-1,2-phenylenediamine) have been synthesized, and characterized by single crystal X-ray diffraction, UV/vis/NIR spectroscopy, and cyclic voltammetry. These studies reveal the enhanced stabilization of Pu(iv) versus Ce(iv) with this Schiff base, and quasi-reversible redox behaviour only with the plutonium complex.

引用

页码：8634 / 8636

页数：3

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