Palladium/norbornene chemistry: an unexpected route to methanocarbazole derivatives via three Csp3-Csp2/Csp3-N/Csp2-N bond formations in a single synthetic sequence

被引：28
|
作者：
Jafarpour, Farnaz [1 ]
Jalalimanesh, Nafiseh [1 ]
Teimouri, Mahdieh [1 ]
Shamsianpour, Mitra [1 ]
机构：
[1] Univ Tehran, Coll Sci, Sch Chem, Tehran, Iran
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 01期
关键词：
TETRASUBSTITUTED HELICAL ALKENES; PALLADIUM-CATALYZED SYNTHESIS; ONE-STEP SYNTHESIS; C-H AMINATION; ARYL IODIDES; DIRECT ARYLATION; EXPEDITIOUS SYNTHESIS; SOLAR-CELLS; O-TERARYLS; FUNCTIONALIZATION;
D O I：
10.1039/c4cc06789d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A Catellani reaction terminated by palladacycle amination leading to methanocarbazoles is reported. The outcome is the formation of three different Csp(3)-Csp(2)/Csp(3)-N/Csp(2)-N bonds through a Heck reaction/C-H activation/double amination cascade in one process.
引用
收藏
页码：225 / 228
页数：4
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