Synthesis and Crystal Structure Characterization of 3,5-Bis(2-quinolyl)-1,2,4-triazole

被引：11

作者：

Cheng, Hui-Min ^{[1
]}

Zhu, Dun-Ru ^{[1
,2
]}

Lu, Wei ^{[1
]}

Xu, Ren-Hui ^{[1
]}

Shen, Xuan ^{[1
]}

机构：

[1] Nanjing Univ Technol, State Key Lab Mat Oriented Chem Engn, Coll Chem & Chem Engn, Nanjing 210009, Jiangsu, Peoples R China

[2] Huaiyin Normal Univ, Jiangsu Key Lab Chem Low Dimens Mat, Huaian 223300, Jiangsu, Peoples R China

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 2010年 / 47卷 / 01期

基金：

中国国家自然科学基金;

关键词：

DINUCLEAR NICKEL(II) COMPLEX; MAGNETIC-PROPERTY; CHEMISTRY;

D O I：

10.1002/jhet.262

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first quinolyl substituted 1,2,4-triazole, 3,5-bis(2-quinolyl)-1,2,4-triazole (4), was synthesized from 2-cyanoquinoline (1) through an intermediate 2-quinolylhydrazidine (2) with 60.4% yield in a simple way. In the synthetic process of 4, another new intermediate, 1,4-diamino-1,4-bis(2-quinolyl)-2,3-diaza-1,3-butadiene (3) was obtained in a yield of 81.5%. Additionally, the absolute configurations of both 3 and 4 were determined by X-ray crystallography.

引用

页码：210 / 213

页数：4

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