Expeditious and stereoselective synthesis of chiral trans-β-hydroxy-δ-lactone systems

被引：18

作者：

Miyazawa, M ^{[1
]}

Matsuoka, E ^{[1
]}

Sasaki, S ^{[1
]}

Oonuma, S ^{[1
]}

Maruyama, K ^{[1
]}

Miyashita, M ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 060, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 02期

关键词：

D O I：

10.1246/cl.1998.109

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Expeditious and stereoselective synthesis of chiral trans-beta-hydroxy-delta-lactone systems starting from gamma,delta-epoxy acrylates is described which involves the regioselective ring opening of an epoxide and the intramolecular conjugate addition of a hemiacetal alkoxide anion of delta-hydroxy-alpha,beta-unsaturated esters as key steps.

引用

页码：109 / 110

页数：2

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