Asymmetric organic synthesis with stoichiometric transition metal complexes

被引：1

作者：

Malinakova, Helena C. ^{[1
]}

机构：

[1] Univ Kansas, Dept Chem, 1140 Gray Little Hall,1567 Irving Hill Rd, Lawrence, KS 66045 USA

来源：

ARKIVOC | 2021年

关键词：

Stoichiometric transition metal-complexes; planar chirality; metal-mediated dearomatization; metal-mediated C-H activation; nucleophilic attack on polyhapto-coordinated ligands; asymmetric synthesis of heterocycles; MOLYBDENUM PI-COMPLEXES; ENANTIOCONTROLLED SYNTHESIS; CHIRAL SCAFFOLDS; TRISUBSTITUTED PIPERIDINES; ENANTIOSELECTIVE SYNTHESIS; MEDIATED DEAROMATIZATION; CONSTRUCTION; ETA(3)-PYRANYL; PALLADACYCLES; DERIVATIVES;

D O I：

10.24820/ark.5550190.p011.454

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Significant recent contributions to the advancement of asymmetric organic synthesis featuring transformations of stoichiometric transition metal complexes are described. Studies that led to the development of powerful synthetic methodologies, as well as projects aimed at elucidation of relevant fundamental concepts, are included. A particular emphasis is placed on applications of complexes with planar chirality. [GRAPHICS]

引用

页码：157 / 184

页数：28

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